(Supra)molecular Inorganic Materials

© 2017 The Cozzolino Research Group.   TTU Chemistry and Biochemistry  |  TTU

Cozzolino Group
  1. Tahmouresilerd, B.; Moody, M.; Agogo, L.; F. Cozzolino, A. The Impact of an Isoreticular Expansion Strategy on the Performance of Iodine Catalysts Supported in Multivariate Zirconium and Aluminum Metal–Organic Frameworks. Dalton Transactions 2019, 48 (19), 6445–6454.
  2. Larson, P. J.; Wekesa, F. S.; Singh, A.; Smith, C. R.; Rajput, A.; McGovern, G. P.; Unruh, D. K.; Cozzolino, A. F.; Findlater, M. Synthesis, Characterization, Electrochemical Properties and Theoretical Calculations of (BIAN) Iron Complexes. Polyhedron 2019, 159, 365–374. https://doi.org/10.1016/j.poly.2018.11.060.
  3. Tamang, S. R.; Cozzolino, A. F.; Findlater, M. Iron Catalysed Selective Reduction of Esters to Alcohols. Org. Biomol. Chem. 2018. https://doi.org/10.1039/C8OB02661K.
  4. Tahmouresilerd, B.; Larson, P. J.; Unruh, D. K.; Cozzolino, A. F. Make Room for Iodine: Systematic Pore Tuning of Multivariate Metal–Organic Frameworks for the Catalytic Oxidation of Hydroquinones Using Hypervalent Iodine. Catal. Sci. Technol. 2018, 8 (17), 4349–4357.
  5. Qiu, J.; Song, B.; Li, X.; Cozzolino, A. F. Solution and Gas Phase Evidence of Anion Binding through the Secondary Bonding Interactions of a Bidentate Bis-Antimony(III) Anion Receptor. Phys. Chem. Chem. Phys. 2018, 20 (1), 46–50.
  6. Moaven, S.; Yu, J.; Vega, M.; Unruh, D. K.; Cozzolino, A. F. Self-Assembled Reversed Bilayers Directed by Pnictogen Bonding to Form Vesicles in Solution. Chem. Commun. 2018, 54 (64), 8849–8852.
  7. Loya, J. D.; Qiu, J.; Unruh, D. K.; Cozzolino, A. F.; Hutchins, K. M. Co-Crystallization of the Anti-Cholesterol Drug Bezafibrate: Molecular Recognition of a Pharmaceutical Contaminant in the Solid State and Solution via Hydrogen Bonding. Crystal Growth & Design 2018, 18 (9), 4838–4843.
  8. Larson, P. J.; Cheney, J. L.; French, A. D.; Klein, D. M.; Wylie, B. J.; Cozzolino, A. F. Anchored Aluminum Catalyzed Meerwein–Ponndorf–Verley Reduction at the Metal Nodes of Robust MOFs. Inorg. Chem. 2018, 57 (12), 6825–6832.
  9. Andrews, M. C.; Peng, P.; Rajput, A.; Cozzolino, A. F. Modulation of the Carboxamidine Redox Potential through Photoinduced Spiropyran or Fulgimide Isomerisation. Photochem. Photobiol. Sci. 2018, 17 (4), 432–441.
  10. Anderson, K. N.; Moaven, S.; Unruh, D. K.; Cozzolino, A. F.; D’Auria, J. C. Improved Synthesis of N-Methylcadaverine. Molecules 2018, 23 (5), 1216.
  11. Moaven, S.; Yu, J.; Yasin, J.; Unruh, D. K.; Cozzolino, A. F. Precise Steric Control over 2D versus 3D Self-Assembly of Antimony(III) Alkoxide Cages through Strong Secondary Bonding Interactions. Inorg. Chem. 2017, 56 (14), 8372–8380.
  12. Cetin, M. M.; Hodson, R. T.; Hart, C. R.; Cordes, D. B.; Findlater, M.; Jr, D. J. C.; Cozzolino, A. F.; Mayer, M. F. Characterization and Photocatalytic Behavior of 2,9-Di(Aryl)-1,10-Phenanthroline Copper(I) Complexes. Dalton Trans. 2017, 46 (20), 6553–6569.
  13. Qiu, J.; Unruh, D. K.; Cozzolino, A. F. Design, Synthesis, and Structural Characterization of a Bisantimony(III) Compound for Anion Binding and the Density Functional Theory Evaluation of Halide Binding through Antimony Secondary Bonding Interactions. J. Phys. Chem. A 2016, 120 (46), 9257–9269.


Publications

  1. Cozzolino, A. F.; Brozek, C. K.; Palmer, R. D.; Yano, J.; Li, M.; Dinca, M. Ligand Redox Non-Innocence in the Stoichiometric Oxidation of Mn 2 (2,5-Dioxidoterephthalate) (Mn-MOF-74). J. Am. Chem. Soc. 2014, 136, 3334–3337.
  2. Cozzolino, A. F.; Silvia, J. S.; Lopez, N.; Cummins, C. C. Experimental and computational studies on the formation of cyanate from early metal terminal nitrido ligands and carbon monoxide. Dalton Trans. 2014, 43, 4639–4652.
  3. Shustova, N. B.; Cozzolino, A. F.; Reineke, S.; Baldo, M.; Dincă, M. Selective Turn-on Ammonia Sensing Enabled by High-Temperature Fluorescence in Metal-Organic Frameworks with Open Metal Sites. J. Am. Chem. Soc. 2013, 135, 13326–13329.
  4. Brozek, C. K.; Cozzolino, A. F.; Teat, S. J.; Chen, Y.-S.; Dinca, M. Quantification of Site-Specific Cation Exchange in Metal-Organic Frameworks using Multi-Wavelength Anomalous X-ray Dispersion. Chem. Mater. 2013, 10.1021/cm400858d.
  5. Palluccio, T. D.; Rybak-Akimova, E. V; Majumdar, S.; Cai, X.; Chui, M.; Temprado, M.; Silvia, J. S.; Cozzolino, A. F.; Tofan, D.; Cummins, C. C.; Captain, B.; Hoff, C. D.; Velian, A. Thermodynamic and Kinetic Study of Cleavage of the N-O Bond of N-oxides by a Vanadium(III) Complex: Enhanced Oxygen Atom Transfer Reaction Rates for Adducts of Nitrous Oxide and Mesityl Nitrile Oxide. J. Am. Chem. Soc. 2013, 10.1021/ja405395z.
  6. Cozzolino, A. F.; Elder, P. J. W.; Lee, L. M.; Vargas-Baca, I. The Role of the Lewis Acid−base Properties in the Supramolecular Association of 1,2,5-Chalcogenadiazoles. Can. J. Chem. 2013, 91, 338–347.
  7. Cozzolino, A. F.; Dimopoulos-Italiano, G.; Lee, L. M.; Vargas-Baca, I. Chalcogen-Nitrogen Secondary Bonding Interactions in the Gas Phase - Spectrometric Detection of Ionized Benzo-2,1,3-telluradiazole Dimers. Eur. J. Inorg. Chem. 2013, 2013, 2751–2756.
  8. Shustova, N. B.; Ong, T.-C.; Cozzolino, A. F.; Michaelis, V. K.; Griffin, R. G.; Dincă, M. Phenyl Ring Dynamics in a Tetraphenylethylene-bridged Metal-organic Framework: Implications for the Mechanism of Aggregation-induced Emission. J. Am. Chem. Soc. 2012, 134, 15061–15070.
  9. Cozzolino, A. F.; Tofan, D.; Cummins, C. C.; Temprado, M.; Palluccio, T. D.; Rybak-Akimova, E. V.; Majumdar, S.; Cai, X.; Captain, B.; Hoff, C. D. Two-step Binding of O2 to a Vanadium(III) Trisanilide Complex to form a Non-vanadyl Vanadium(V) Peroxo Complex. J. Am. Chem. Soc. 2012, 134, 18249–18252.
  10. Elder, P. J. W.; Landry, J. C.; Cozzolino, A. F.; Chapman, A. E. A.; Vargas-Baca, I. A Push–pull Azobenzene is Mercurated Twice at the Ring with Less Electron Density. J. Organomet. Chem. 2012, 716, 11–18.
  11. Shustova, N. B.; Cozzolino, A. F.; Dincă, M. Conformational Locking by Design: Relating Strain Energy with Luminescence and Stability in Rigid Metal-organic Frameworks. J. Am. Chem. Soc. 2012, 134, 19596–9.
  12. Curley, J. J.; Cozzolino, A. F.; Cummins, C. C. Nitrogen Fixation to Cyanide at a Molybdenum Center. Dalton Trans. 2011, 40, 2429–32.
  13. Cozzolino, A. F.; Elder, P. J. W.; Vargas-Baca, I. A Survey of Tellurium-centered Secondary-bonding Supramolecular Synthons. Coord. Chem. Rev. 2011, 255, 1426–1438.
  14. Cozzolino, A. F.; Vargas-Baca, I. Parametrization of a Force Field for Te−N Secondary Bonding Interactions and Its Application in the Design of Supramolecular Structures Based on Heterocyclic Building Blocks. Cryst. Growth Des. 2011, 11, 668–677.
  15. Moroz, Y. S.; Cozzolino, A. F.; Rybak-Akimova, E. V; Cummins, C. C. Bis(μ2-η2:η2-2,4,6-trimethyl-benzonitrile)-bis-[(N-isopropyl-3,5-dimethyl-anilido)molybdenum(III)](Mo-Mo). Acta Crystallogr., Sect. E 2011, 67, m1643–m1644.
  16. Cozzolino, A. F.; Yang, Q.; Vargas-Baca, I. Engineering Second-Order Nonlinear Optical Activity by Means of a Noncentrosymmetric Distortion of the [Te−N]2 Supramolecular Synthon. Cryst. Growth Des. 2010, 10, 4959–4964.
  17. Cozzolino, A. F.; Whitfield, P. S.; Vargas-Baca, I. Supramolecular Chromotropism of the Crystalline Phases of 4,5,6,7-Tetrafluorobenzo-2,1,3-telluradiazole. J. Am. Chem. Soc. 2010, 132, 17265–17270.
  18. Lee, L. M.; Elder, P. J. W.; Cozzolino, A. F.; Yang, Q.; Vargas-Baca, I. An Experimental and Computational Investigation of the Formation and Structures of N-Hydro- and N,N’-Dihydro-benzo-2,1,3-chalcogenadiazolium Chlorides. Main Group Chem. 2010, 9, 117–133.
  19. Cozzolino, A. F.; Bain, A. D.; Hanhan, S.; Vargas-Baca, I. N-Triphenylboryl- and N,N’-Bis(triphenylboryl)benzo-2,1,3-telluradiazole. Chem. Commun. 2009, 8, 4043–4045.
  20. Ogini, F. O.; Ortin, Y.; Mahmoudkhani, A. H.; Cozzolino, A. F.; McGlinchey, M. J.; Vargas-Baca, I. An Investigation of the Formation of 1,3,5-Heterosubstituted Benzene Rings by Cyclo-condensation of Acetyl-substituted Organometallic Complexes. J. Organomet. Chem. 2008, 693, 1957–1967.
  21. Cozzolino, A. F.; Gruhn, N. E.; Lichtenberger, D. L.; Vargas-Baca, I. Valence Electronic Structure of Benzo-2,1,3-chalcogenadiazoles Studied by Photoelectron Spectroscopy and Density Functional Theory. Inorg. Chem. 2008, 47, 6220–6226.
  22. Cozzolino, A. F.; Vargas-Baca, I. The Supramolecular Chemistry of 1,2,5-Chalcogenadiazoles. J. Organomet. Chem. 2007, 692, 2654–2657.
  23. Cozzolino, A. F.; Britten, J. F.; Vargas-Baca, I. The Effect of Steric Hindrance on the Association of Telluradiazoles through Te−N Secondary Bonding Interactions. Cryst. Growth Des. 2006, 6, 181–186.
  24. Cozzolino, A. F.; Vargas-Baca, I.; Mansour, S.; Mahmoudkhani, A. H. The Nature of the Supramolecular Association of 1,2,5-Chalcogenadiazoles. J. Am. Chem. Soc. 2005, 127, 3184–3190.
  25. Zhang, W.; Cozzolino, A. F.; Mahmoudkhani, A. H.; Tulumello, M.; Mansour, S.; Vargas-Baca, I. Influence of pi-Stacking on the Resonant Enhancement of the Second-Order Nonlinear Optical Response of Dipolar Chromophores. J. Phys. Chem., B 2005, 109, 18378–84.

Publications from B.Sc., Ph.D. and Postdoctoral Studies

Publications from Texas Tech